WebThe chain growth probability (alpha value) is one of the most significant parameters in Fischer-Tropsch (FT) synthesis. To gain insight into the chain growth probability, we systematically studied the hydrogenation and C-C coupling reactions with different chain lengths on the stepped Co(0001) surface using density functional theory calculations. WebJul 1, 2008 · The chain growth probability (α value) is one of the most significant parameters in Fischer–Tropsch (FT) synthesis. To gain insight into the chain growth probability, we systematically studied the hydrogenation and C C coupling reactions with different chain lengths on the stepped Co(0001) surface using density functional theory …
Probability of chain growth - Big Chemical Encyclopedia
WebJun 17, 2013 · Since the overall chain growth probability strongly depends on the rate of CO to CH x transformation as well as the rate of CH x hydrogenation to methane, a change in the chemistry of the reactive center that affects the relative rate of CO dissociation will have a major effect on the chain growth probability α. We have discussed that on small ... WebThe C 5+ space time yield, a combination of catalyst activity and selectivity, can be increased with a factor 3 (small catalyst particle, dcat = 50 μm) to 10 (large catalyst particle, dcat = 2.0 mm) by lowering the bulk H 2 /CO ratio from 2 to 1, and increasing temperature from 500 K to 530 K. flesch reading ease to grade level
Some Understanding of Fischer–Tropsch Synthesis from
WebChain growth probability factor The description of the product distribution for an FT reaction can be simplified and described by the use of a single parameter (a value) determined from the Anderson-Schulz-Flory (ASF) plots. The a value (also called the chain growth probability factor) is then used to describe the total product spectrum in terms … WebFeb 9, 2010 · The sudden jump of the chain growth probability with n = 2 is the result of the anomaly of the ethane/ethylene ratio. The low chain growth probability for n = 1 is related to the slower chain growth rate than those with n ≥ 2. (iv) CH 4 selectivity correlates with the adsorption energy of C + 4H. WebThe chain growth probability of Fischer-Tropsch synthesis (FTS) was investigated on the basis of data from a set of experiments over an industrial coprecipitated Fe−Cu−K catalyst developed by the Institute of Coal Chemistry (China). The experimental results show that the ASF chain growth probability (α) depends on operation conditions, temperature (T) … flesch reading ease score free